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Journal Articles

Electronic properties of 6,13-Bis(triisopropylsilylethynyl)pentacene probed by inner-shell spectroscopy

Ikeura, Hiromi*; Sekiguchi, Tetsuhiro

Molecular Crystals and Liquid Crystals, 622(1), p.50 - 54, 2015/12

BB2014-1633.pdf:0.39MB

 Times Cited Count:0 Percentile:0.01(Chemistry, Multidisciplinary)

Organic electrically conducting $$pi$$-stacked molecules are widely regarded as promising materials for future application of nanoelectronics. Direct measurements of electronic structures of unoccupied states in organic semiconductors lead to better understanding of mechanism of electron conduction. For probing unoccupied partial density of states (DOS), X-ray absorption spectroscopy (XAS) is commonly used, where selective excitation of the 1s core electron to the unoccupied conduction band is possible. However, XAS cannot distinguish localized and delocalized features without comparing any theoretical approach. In this work, the core-hole-clock method in resonant Auger spectroscopy (RAS) has been applied to probe electron delocalization through the empty conduction band in the attosecond domain for the purpose of exploring electronic materials with high-speed electron transport. We will discuss some organic molecules such as pentacenes.

Journal Articles

Resonant Auger transitions and ion desorption following S-1s excitation in condensed CS$$_{2}$$

Yoshii, Kenji; Baba, Yuji; Sasaki, Teikichi

Journal of Electron Spectroscopy and Related Phenomena, 93, p.105 - 108, 1998/00

 Times Cited Count:2 Percentile:11.16(Spectroscopy)

no abstracts in English

Journal Articles

Electronic structures of phosphates studied by TEY-XANES and resonant AES

*; Noro, Hisato*; Nagoshi, Masayasu*; Yamamoto, Hiroyuki; Baba, Yuji; Sasaki, Teikichi

Journal of Electron Spectroscopy and Related Phenomena, 88-91, p.467 - 471, 1998/00

 Times Cited Count:9 Percentile:41.19(Spectroscopy)

no abstracts in English

Journal Articles

Resonant auger electron spectra at Si-, P-, S-, and Cl-1s thresholds of condensed molecules

Yoshii, Kenji; Baba, Yuji; Sasaki, Teikichi

Physica Status Solidi (B), 206, p.811 - 822, 1998/00

 Times Cited Count:11 Percentile:53.44(Physics, Condensed Matter)

no abstracts in English

Journal Articles

XANES and resonant AES for phosphates

Okude, Nobuya*; Noro, Hisato*; Nagoshi, Masayasu*; Yamamoto, Hiroyuki; Baba, Yuji; Sasaki, Teikichi

Photon Factory Activity Report, (14), P. 430, 1996/00

no abstracts in English

Journal Articles

S(KLL) resonant Auger decay in mono- and multi-layered CS$$_{2}$$

Yoshii, Kenji; Baba, Yuji; Sasaki, Teikichi

Hyomen Kagaku, 16(7), p.453 - 457, 1995/07

no abstracts in English

Journal Articles

LMM Resonant-auger decay processes in 4d-transition metal oxides(Y$$_{2}$$O$$_{3}$$,ZrO$$_{2}$$,Nb$$_{2}$$O$$_{5}$$)

Yoshii, Kenji; Baba, Yuji; Sasaki, Teikichi

Hyomen Kagaku, 15(5), p.295 - 299, 1994/07

no abstracts in English

Oral presentation

Electronic structures of sulfur-containing organic electronic materials probed by X-ray absorption spectroscopy

Ikeura, Hiromi*; Sekiguchi, Tetsuhiro

no journal, , 

Many peaks are observed in X-ray absorption fine structure near the inner-shall edges. Such fine structures are called near-edge X-rays absorption fine structure or abbreviated as NEXAFS. NEXAFS spectra provide us with information on property of electronic states concerning partial density of states of unoccupied conduction band for materials. In this work, we have investigated several sulfur-containing thiophene derivative polymers using NEXAFS spectroscopy. We have recorded the S K-edge NEXAFS spectra of film samples of these electronic materials and tried to interpret the origin of electronic transition seen in NEXAFS on the basis of molecular orbital theory. Furthermore, we discuss whether there is a potential relation between the observed spectra and charge-transfer property of the materials.

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